1246451-81-9Relevant academic research and scientific papers
Palladium-catalyzed γ-arylation of α,β-unsaturated esters from silyl ketene acetals
Huang, David S.,Hartwig, John F.
supporting information; experimental part, p. 5757 - 5761 (2010/11/02)
(Figure Presented) Smarty cat: A method for the palladiumcatalyzed γ-arylation of α,β-unsaturated esters via silyl ketene acetals in the absence of fluoride has been developed. The coupling proceeds with electron-rich and electron-poor aryl bromides and vinyl bromides in high yields with a high tolerance for other functional groups.
