1246517-85-0Relevant academic research and scientific papers
[CoCl(TPPyP)], a novel bifunctional catalyst for the coupling reaction of carbon dioxide and propylene oxide
Ren, Tiegang,Li, Weijie,Bu, Zhanwei,Yang, Lirong,Wang, Zhiqiang
experimental part, p. 361 - 364 (2010/11/03)
A novel bifunctional catalyst chloro[meso-tetrakis(1-phenylpyrazol-4-yl) porphyrin] cobalt(III), [CoCl(TPPyP)], has been prepared and used to catalyse the synthesis of propylene carbonate from carbon dioxide and propylene oxide under mild conditions. Propylene carbonate was obtained with a yield of 25.2% at 100 °C in the absence of co-catalyst. A reaction mechanism is proposed.
