124658-85-1

Upstream product

• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 4083-64-1 Tosyl isocyanate 
• 6246-48-6 geranylamine 
• 98-59-9 p-toluenesulfonyl chloride 
• 124658-92-0 ethyl N-geranyl-N-tosylcarbamate 
• 5577-13-9 Tosylurethane 
• 6138-90-5 trans-geranyl bromide 

Downstream Products

• 727423-31-6 (E)-N-(3,7-dimethylocta-2,6-dien-1-yl)-4-methyl-N-(prop-2-yn-1-yl)benzenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 78388-19-9 4-methyl-N-(3-methylbut-2-enyl)benzenesulfonamide 
• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 
• 1576-37-0 N-benzyl-p-toluenesulfonamide 
• 135979-17-8 N-allyl-4-methyl-N-(3-methylbut-2-en-1-yl)benzenesulfonamide 

Relevant academic research and scientific papers

Iodine(III)-mediated halogenations of acyclic monoterpenoids

Five different halofunctionalizations of acyclic monoterpenoids were performed using a combination of a hypervalent iodine(III) reagent and a halide salt. In this manner, the dibromination, the bromo(trifluoro)acetoxylation, the bromohydroxylation, the iodo(trifluoro)acetoxylation or the ene-type chlorination of the distal trisubstituted double bond occurred with excellent selectivity and moderate to good yields.

Gold(I)-catalyzed highly regio- and stereoselective decarboxylative amination of allylic N-tosylcarbamates via base-induced aza-Claisen rearrangement in water

(Figure Presented)A gold(l)-catalyzed decarboxylative animation of allylic N-tosylcarbamates via base-induced aza-Claisen rearrangement has been developed. A variety of substituted W-tosyl allylic amines were obtained In good yield, excellent regloselectlvity, and high to excellent stereoselectivity. This transformation could be performed either in H2O or In one pot directly from allylic alcohols and therefore represents an efficient and environmentally benign protocol for the synthesis of N-tosyl allylic amines.

One-Pot Synthesis of Tetrahydrofuran Derivatives from Allylic Alcohols and Vinyl Ethers by Means of Palladium(II) Acetate

Reaction of allylic alcohol with vinyl ether in the presence of Pd(OAc)2 afforded furan derivatives in good yield.Pd(OAc)2 was essential for the reaction.PdCl2 complex did not afford cyclized product but gave acetal exclusively.Three components were combined at once to produce 4-(3-butenyl)-2-butoxy-4-methyltetrahydrofuran upon treatment of a mixture of 2-methyl-2-propen-1-ol, butyl vinyl ether, and allyl bromide.The reaction could successfully be extended to the synthesis of nitrogen containing heterocycles by use of N-tosyl allylic amines in place of allylic alcohols.