1246609-35-7

Basic information

• Product Name: C₁₄H₂₂N₂O₂PS₂^(1-)*C₂₄H₂₀P⁽¹⁺⁾
• Synonyms: C₁₄H₂₂N₂O₂PS₂^(1-)*C₂₄H₂₀P⁽¹⁺⁾
• CAS NO: 1246609-35-7
• Molecular Weight: 684.843
• Mol File: 1246609-35-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₂N₂O₂PS₂^(1-)*C₂₄H₂₀P⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₂N₂O₂PS₂^(1-)*C₂₄H₂₀P⁽¹⁺⁾(1246609-35-7)
• EPA Substance Registry System: C₁₄H₂₂N₂O₂PS₂^(1-)*C₂₄H₂₀P⁽¹⁺⁾(1246609-35-7)

Safety Data

• Hazardous Substances Data: 1246609-35-7(Hazardous Substances Data)

Upstream product

• 1226638-29-4 2-MeC₆H₄NHC(S)NHP(S)(O(i)Pr)2 
• 24038-30-0 tetraphenylphosphonium bromide 

Relevant articles and documents

Tetraphenylphosphonium salts of N-thiophosphorylated thiobenzamide, mono-thioureas or bis-thioureas

Reaction of the sodium salts of RC(S) NHP(S)(O-i-Pr)2 (R = Ph, HLI; PhNH, HLII; 2-MeC6H4NH, HL III; 2,6-Me2C6H3NH, HLIV; 2,4,6-Me3C6H2NH, HLV) or Z[NHC(S)NHP(S)(O-i-Pr)2]2 (Z = o-C6H 4,H2LVI; 1,2-CH2CH 2,H2LVII) with PPh4Br in 96% aqueous EtOH leads to the compounds of formulae PPh4LI-V and (PPh4)2LVI,VII. Compounds obtained were investigated by 1H and 31P{1H} NMR spectroscopy, ES mass spectrometry, and microanalysis. Recrystallization of PPh4LI from an aqueous EtOH solution (1:1, v/v) leads to the formation of PhC(S)NHP(O)(O-i-Pr)2 (HQ). The crystal structure of HQ reveals to be a polymorph to the previously reported structure.