1246658-60-5Relevant academic research and scientific papers
Site-Selective Csp3-Csp/Csp3-Csp2Cross-Coupling Reactions Using Frustrated Lewis Pairs
Dasgupta, Ayan,Stefkova, Katarina,Babaahmadi, Rasool,Yates, Brian F.,Buurma, Niklaas J.,Ariafard, Alireza,Richards, Emma,Melen, Rebecca L.
, p. 4451 - 4464 (2021/04/07)
The donor-acceptor ability of frustrated Lewis pairs (FLPs) has led to widespread applications in organic synthesis. Single electron transfer from a donor Lewis base to an acceptor Lewis acid can generate a frustrated radical pair (FRP) depending on the s
Bronsted acid ionic liquid as a solvent-conserving catalyst for organic reactions
Taheri, Amir,Pan, Xiaojuan,Liu, Changhui,Gu, Yanlong
, p. 2094 - 2098 (2014/10/15)
A sulfonyl-containing ammonium-based Bronsted acid ionic liquid was prepared and used as a liquid heterogeneous catalyst for organic reactions. The unique macroscopic phase heterogeneity of the IL in the reaction system not only ensures an excellent catalytic activity of the IL catalyst but also avoids the use of organic reaction solvents. The catalyst system is applicable for a wide range of reactions.
Pd-catalyzed three-component coupling of N-Tosylhydrazone, terminal alkyne, and Aryl halide
Zhou, Lei,Ye, Fei,Zhang, Yan,Wang, Jianbo
experimental part, p. 13590 - 13591 (2010/12/29)
A Pd-catalyzed three-component reaction of N-tosylhydrazone, terminal alkyne, and aryl halide follows a mechanism involving a sequence of Pd carbene migratory insertion-transmetalation-reductive elimination, leading to the formation of one sp2-sp3 C-C bond and one sp-sp 3 C-C bond.
