1246665-68-8

Basic information

• Product Name: (2S,3R,6S)-3-ethyl-5-hydroxy-6-methyl-2-tosylcyclohexanone
• Synonyms: (2S,3R,6S)-3-ethyl-5-hydroxy-6-methyl-2-tosylcyclohexanone
• CAS NO: 1246665-68-8
• Molecular Weight: 310.414
• Mol File: 1246665-68-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3R,6S)-3-ethyl-5-hydroxy-6-methyl-2-tosylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,6S)-3-ethyl-5-hydroxy-6-methyl-2-tosylcyclohexanone(1246665-68-8)
• EPA Substance Registry System: (2S,3R,6S)-3-ethyl-5-hydroxy-6-methyl-2-tosylcyclohexanone(1246665-68-8)

Safety Data

• Hazardous Substances Data: 1246665-68-8(Hazardous Substances Data)

Upstream product

• 1576-86-9 2-pentenal 
• 66947-20-4 1-(p-Tolylsulfonyl)-2-butanone 

Downstream Products

• 1246665-77-9 (5R,6S)-5-ethyl-2-methyl-6-(p-tolylsulfonyl)cyclohex-2-enone 

Relevant articles and documents

Influence of the reaction conditions on the evolution of the michael addition of β-keto sulfones to α,β-unsaturated aldehydes

We have studied the influence of different reaction conditions on the conjugated addition of β-keto sulfones to a,βunsaturated aldehydes catalyzed by silyl prolinol ethers. Small changes in the starting material and/or in the experimental protocol are able to produce significant variations in the structures of the final products. The high chemical versatility of the resulting Michael adducts make possible their use in a variety of tandem and one-pot reactions to afford polysubstituted cyclic products bearing multiple chiral centers.