1246776-02-2Relevant articles and documents
Stereoselective synthesis of ring C-hexasubstituted trianglamines
Savoia, Diego,Gualandi, Andrea,Stoeckli-Evans, Helen
, p. 3992 - 3996 (2010)
The addition of organolithium reagents to the trianglimine derived from (R,R)-1,2-diaminocyclohexane and terephthalaldehyde gave the corresponding trianglamine with complete stereocontrol and the R configuration of all six newly formed stereocenters. The structure of the hexaphenyl-substituted macrocyle was determined by X-ray crystallographic study. The new trianglamines were tested as ligands in enantioselective catalytic reactions.