1246809-85-7Relevant academic research and scientific papers
Regiodivergent epoxide opening (REO) via electron transfer: Control elements
Gansaeuer, Andreas,Shi, Lei,Keller, Florian,Karbaum, Peter,Fan, Chun-An
, p. 1361 - 1369 (2010)
The first regiodivergent opening of unbiased epoxides (REO) providing the ring-opened products in high enantiomeric excess from racemic and exceptionally high enantiomeric excess from enantioenriched substrates in a double asymmetric process has been devised. It constitutes a more general case of the very important enantioselective openings of meso-epoxides. The dependence of the selectivity of ring opening on the epoxides substitution pattern was studied.
