1246927-46-7Relevant academic research and scientific papers
Enantioselective rhodium-catalyzed synthesis of branched allylic amines by intermolecular hydroamination of terminal allenes
Cooke, Michael L.,Xu, Kun,Breit, Bernhard
supporting information, p. 10876 - 10879 (2013/01/15)
Branching out: The rhodium-catalyzed enantioselective hydroamination of monosubstituted allenes with anilines permits the atom-economic synthesis of valuable branched allylic amines. In contrast to previous linear selective allene hydroaminations, a Rhsu
Rhodium-catalyzed regioselective amination of secondary allylic trichloroacetimidates with unactivated aromatic amines
Arnold, Jeffrey S.,Stone, Robert F.,Nguyen, Hien M.
supporting information; experimental part, p. 4580 - 4583 (2010/12/24)
The use of unactivated aromatic amines in the rhodium-catalyzed regioselective amination of secondary allylic trichloroacetimidates is explored. The desired N-arylamines are obtained in high yields and regioselectivity, favoring the branched amination pro
