1247014-79-4Relevant academic research and scientific papers
One-pot synthesis of mononuclear iron alkynyl complexes by photolysis
Argouarch, Gilles,Grelaud, Guillaume,Paul, Frederic
, p. 4414 - 4416 (2010)
A new access to organoiron complexes of type (dppe)Cp*Fe-C≡C-Ar (3) from the easily prepared precursor (CO)2Cp*FeCl (5) is described. This direct one-pot transformation realized upon UV irradiation is illustrated by various aromatic alkynes. A mechanism is also proposed for this reaction via the key intermediate [(dppe)Cp*Fe(CO)][PF6] (6).
