124740-34-7

Basic information

• Product Name: N-Methyl-3-Methyl-N-phenylbenzaMide, 97%
• Synonyms: N-Methyl-3-Methyl-N-phenylbenzaMide, 97%;N,3-dimethyl-N-phenylbenzamide
• CAS NO: 124740-34-7
• Molecular Formula: C₁₅H₁₅NO
• Molecular Weight: 225.2857
• Mol File: 124740-34-7.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Methyl-3-Methyl-N-phenylbenzaMide, 97%(CAS DataBase Reference)
• NIST Chemistry Reference: N-Methyl-3-Methyl-N-phenylbenzaMide, 97%(124740-34-7)
• EPA Substance Registry System: N-Methyl-3-Methyl-N-phenylbenzaMide, 97%(124740-34-7)

Safety Data

• Hazardous Substances Data: 124740-34-7(Hazardous Substances Data)

Upstream product

• 107918-13-8 N-(3-methylbenzoyl)saccharin 
• 121-69-7 N,N-dimethyl-aniline 
• 1711-06-4 3-Methylbenzoyl chloride 
• 99-36-5 1-methoxycarbonyl-3-methylbenzene 
• 100-61-8 N-methylaniline 
• 201230-82-2 carbon monoxide 
• 625-95-6 3-Iodotoluene 
• 20821-70-9 O-(3-methylphenyl) N-methyl-N-phenyl thiocarbamate 

Downstream Products

• 23099-05-0 3-methyl-N-phenylbenzamide 
• 99-04-7 m-Toluic acid 
• 99-36-5 1-methoxycarbonyl-3-methylbenzene 

Relevant articles and documents

Nickel-Catalyzed Oxidative Transamidation of Tertiary Aromatic Amines with N -Acylsaccharins

The use of tertiary amines as surrogates for secondary amines has prominent advantages in terms of stabilization and ease of handling. A Ni-catalyzed transamidation of N -acylsaccharins with tertiary aromatic amines is reported. By using tert -butyl hydroperoxide as the terminal oxidant, this reaction permits selective cleavage of the C(sp 3)-N bonds of unsymmetrical tertiary aromatic amines depending on the sizes of the alkyl substituents.

KMnO4-mediated oxidative C[sbnd]N bond cleavage of tertiary amines: Synthesis of amides and sulfonamides

KMnO4-mediated oxidative C[sbnd]N bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.

DIRECT CONVERSION OF PHENOLS INTO AMIDES AND ESTERS OF BENZOIC ACID

A method is provided for the preparation of an aromatic carboxylic acid aryl ester or an N-aryl aromatic carboxamide. The method comprises contacting an O,O-diaryl thiocarbonate or an O-aryl-N-aryl thiocarbamate with a reactant that regioselectively reacts with sulfur, which contact causes an O-neophyl rearrangement, thereby forming either the aromatic carboxylic acid aryl ester or the N-aryl aromatic carboxamide, respectively.