1247748-11-3

Basic information

• Product Name: S-2,6-dimethylphenyl α-bromothiopropionate
• Synonyms: S-2,6-dimethylphenyl α-bromothiopropionate
• CAS NO: 1247748-11-3
• Molecular Weight: 273.194
• Mol File: 1247748-11-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: S-2,6-dimethylphenyl α-bromothiopropionate(CAS DataBase Reference)
• NIST Chemistry Reference: S-2,6-dimethylphenyl α-bromothiopropionate(1247748-11-3)
• EPA Substance Registry System: S-2,6-dimethylphenyl α-bromothiopropionate(1247748-11-3)

Safety Data

• Hazardous Substances Data: 1247748-11-3(Hazardous Substances Data)

Upstream product

• 118-72-9 2,6-dimethylbenzene-1-thiol 
• 563-76-8 α-bromopropionyl bromide 

Downstream Products

• 1247747-91-6 S-2,6-dimethylphenyl α-iodothiopropionate 
• 1256358-40-3 2-(triphenylphosphoranylidene)propanethioic acid S-(2,6-dimethylphenyl) ester 

Relevant articles and documents

Cu(II)-catalyzed acylation by thiol esters under neutral conditions: Tandem acylation-wittig reaction leading to a one-pot synthesis of butenolides

The first catalytic acylation of alcohols with a thiol ester present in Wittig reagents under neutral conditions catalyzed by the Cu(II) salt through a push-pull mechanism is reported. Furthermore, a new methodology for the one-pot lactonization of acyloins by a copper catalyst is developed. The synthetic utility of this method for the synthesis of natural products is shown.