1247764-37-9Relevant academic research and scientific papers
Reactivity of the bis(silyl) palladium(II) complex toward organic isothiocyanates
Kim, Yong-Joo,Jeon, Hyung-Tak,Lee, Kyung-Eun,Lee, Soon W.
, p. 2258 - 2263 (2010)
The bis(silyl) palladium(II) complex [Pd(SiHPh2) 2(dmpe)] (dmpe = 1,2-bis(dimethylphosphino)ethane) reacted with organic isothiocyanates R-NCS (R = Ph, iPr, allyl) to give a dithiocarbonimidato [Pd(S2CN-Ph)(dmpe)] (1), a diphenylsilanedithiolato [Pd(S2SiPh2)(dmpe)] (2), or a π-allyl [(η3-allyl)Pd](NCS) (3) palladium complex, depending on the isothiocyanate type and reaction conditions. In addition, various dithiocarbonimidato Pd(II) complexes were also obtained from trans-[PdEt 2L2] (L = PMe3, PMe2Ph) (4-6) or [Pd(styrene)L2] and organic isothiocyanates.
