124778-25-2Relevant academic research and scientific papers
Amino Acid Esters as Chiral Auxiliaries in Barbier-Type Reactions in Aqueous Solution
Waldmann, Herbert
, p. 1317 - 1322 (2007/10/02)
Valine and proline benzyl ester are converted into the aliphatic and aromatic α-oxo amides 5 by activation of the respective α-oxo acid by means of N,N'-diisopropylcarbodiimide.The α-oxo amides 5 undergo Barbier-type reactions with differently substituted
Stereochimie de la reduction electrochimique d'α-cetoamides optiquement actives II. Electroreduction de benzoylformamides derives de la S(-)-proline
Boulmedais, Ali,Jubault, Michel,Tallec, Andre
, p. 185 - 191 (2007/10/02)
Electrochemical reduction of benzoylformamides derived from S-(-)-proline has been carried out at a mercury cathode in a buffered hydroalcoholic medium; quantitative formation of a mixture of the two epimers of the corresponding mandelamides is observed.D
