124789-72-6

Basic information

• Product Name: Silane, bis(chloromethyl)methylphenyl-
• CAS NO: 124789-72-6
• Molecular Formula: C9H12Cl2Si
• Molecular Weight: 219.186
• Mol File: 124789-72-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, bis(chloromethyl)methylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, bis(chloromethyl)methylphenyl-(124789-72-6)
• EPA Substance Registry System: Silane, bis(chloromethyl)methylphenyl-(124789-72-6)

Safety Data

• Hazardous Substances Data: 124789-72-6(Hazardous Substances Data)

Upstream product

• 74-97-5 chlorobromomethane 
• 149-74-6 dichloromethylphenylsilane 
• 591-50-4 iodobenzene 
• 18171-56-7 bis(chloromethyl)(methyl)chlorosilane 

Downstream Products

• 1622406-76-1 chloromethyl((2-iodophenoxy)methyl)(methyl)(phenyl)silane 
• 1622406-78-3 tert-butyl ((chloromethyl)(methyl)(phenyl)silyl)methyl(2-iodophenyl)carbamate 
• 1622406-80-7 C₁₉H₂₄ClIN₂O₂Si 
• 1622406-82-9 3-methyl-3-phenyl-3,4-dihydro-2H-1,3-benzooxasiline 
• 1622407-18-4 4-methyl-4-phenyl-3,4-dihydro-2H-benzo-1,4-oxasiline 
• 1622406-86-3 tert-butyl 3-methyl-3-phenyl-3,4-dihydropyrido[3,4-e][1,3]azasiline-1(2H)-carboxylate 
• 1622406-87-4 tert-butyl 3,3-diphenyl-3,4-dihydropyrido[3,4-e][1,3]azasiline-1(2H)-carboxylate 
• 1622407-22-0 tert-butyl 3-benzyl-3-phenyl-2,3-dihydro-1H-[1,3]azasilolo[4,5-c]pyridine-1-carboxylate 
• 138421-14-4 2-phenyl-3-isobutyryloxy-2-methyl-2-silapropane-1-ol 
• 138421-14-4 2-phenyl-3-isobutyryloxy-2-methyl-2-silapropane-1-ol 
• 138421-16-6 1,3-disobutyryloxy-2-metyl-2-phenyl-2-silapropan-1-ol 
• 138421-21-3 1,3-diacetoxy-2-methyl-2-phenyl-2-silapropane 

Relevant articles and documents

3-Silaazetidine: An Unexplored yet Versatile Organosilane Species for Ring Expansion toward Silaazacycles

Small-ring silacycles are important organosilane species in main-group chemistry and have found numerous applications in organic synthesis. 3-Silaazetidine, a unique small silacycle bearing silicon and nitrogen atoms, has not been adequately explored due to the lack of a general synthetic scheme and its sensitivity to air. Here, we describe that 3-silaazetidine can be easily prepared in situ from diverse air-stable precursors (RSO2NHCH2SiR12CH2Cl). 3-Silaazetidine shows excellent functional group tolerance in a palladium-catalyzed ring expansion reaction with terminal alkynes, giving 3-silatetrahydropyridines and diverse silaazacycle derivatives, which are promising ring frameworks for the discovery of Si-containing functional molecules.

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Various prochirals silapropan-diols were synthetised with good yields. Several enzymatic-catalysed hydrolyses or transesterification have been attempted on this products; when we change the parameters: as the temperature in transesterification reaction, t