124791-26-0Relevant academic research and scientific papers
New Reagents, XXXIX - Optimization of the Diastereo- and Aldehyde Selectivity of Horner-Type Reagents by Modification of the Structure
Kauffmann, Thomas,Schwartze, Paul
, p. 2150 - 2158 (2007/10/02)
Introduction of an ortho-substituent in the phenyl residues of (α-lithiobutyl)diphenylphosphane oxide (7) increases the diastereoselectivity in the reaction with benzaldehyde. (α-Lithiobutyl)bis(2-methoxyphenyl)phosphane oxide (9) gave the erythro-product
