1248348-95-9

Basic information

• Product Name: phenyl 2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-1-thio-β-D-glucopyranoside
• Synonyms: phenyl 2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-1-thio-β-D-glucopyranoside
• CAS NO: 1248348-95-9
• Molecular Weight: 474.532
• Mol File: 1248348-95-9.mol

Chemical Properties

• CAS DataBase Reference: phenyl 2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-1-thio-β-D-glucopyranoside(1248348-95-9)
• EPA Substance Registry System: phenyl 2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-1-thio-β-D-glucopyranoside(1248348-95-9)

Safety Data

• Hazardous Substances Data: 1248348-95-9(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 273749-60-3 phenyl 4,6-O-(4-methoxybenzylidene)-1-thio-β-D-glucopyranoside 
• 108-98-5 thiophenol 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 83-87-4 D-glucose pentaacetate 
• 2936-70-1 (2R,3S,4S,5R,6S)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4,5-triol 
• 13992-16-0 (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 

Downstream Products

• 1261355-83-2 methyl (2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-β-D-glucopyranosyl)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside 
• 849132-29-2 phenyl 2,3,6-tri-O-acetyl-1-thio-β-D-glucopyranoside 

Relevant articles and documents

Chemical Synthesis of Modified Hyaluronic Acid Disaccharides

Herein we report a chemical synthesis towards new modified hyaluronic acid oligomers by using only commercially available d-glucose and d-glucosamine hydrochloride. The various protected hyaluronic acid disaccharides were synthesized bearing new functional groups at C-6 of the β-d-glucuronic acid moiety with a view to structure-related biological activity tests. The orthogonal protecting group pattern allows ready access to the corresponding higher oligomers. Also, 1H NMR studies of the new derivatives demonstrated the effect of the various functional groups on the intramolecular electronic environment.

Synthesis of the non-reducing end trisaccharide of the antithrombin-binding domain of heparin and its bioisosteric sulfonic acid analogues

A glucoronic acid-containing trisaccharide related to the antithrombin-binding DEFGH domain of heparin and its methanesulfonic acid analogues were synthesized. Trisaccharides without sulfonic acid content or possessing a sulfonatomethyl moiety at position

Synthesis of sulfonic acid analogues of the non-reducing end trisaccharide of the antithrombin binding domain of heparin

Three sulfonic acid trisaccharides related to the antithrombin-binding DEFGH domain of heparin were synthesised. Trisaccharides carrying the sulfonatomethyl moiety at position 2 or 6 were prepared in high yields by [DE+F] couplings using the same disaccha