1248520-41-3Relevant academic research and scientific papers
Total synthesis of plukenetione A
Zhang, Qiang,Mitasev, Branko,Qi, Ji,Porco Jr., John A.
supporting information; experimental part, p. 14212 - 14215 (2010/12/24)
We describe an alkylative dearomatization/acid-mediated adamantane annulation sequence that allows facile access to type A polyprenylated acylphloroglucinol natural products including plukenetione A. Introduction of the 2-methyl-1-propenyl moiety was achieved via stereodivergent SN2 and SN1 cyclizations of allylic alcohol substrates.
