1248568-79-7Relevant academic research and scientific papers
Iridium-Catalyzed Unreactive C(sp3)-H Amination with 2,2,2-Trichloroethoxycarbonyl Azide
Zhang, Tao,Hu, Xuejiao,Dong, Xunqing,Li, Guigen,Lu, Hongjian
supporting information, p. 6260 - 6264 (2018/10/02)
An additive-assisted iridium-catalyzed directed C(sp3)-H amination with 2,2,2-trichloroethoxycarbonyl azide as an amino source is reported. Both carboxylate anions and the corresponding cations in the additives are crucial to achieve satisfactory efficiency. Sodium acetate or n-pentanoic acid can promote the amination of various primary C(sp3)-H bonds adjacent to secondary, tertiary, and quaternary carbons in ketoximes or N-aromatic heterocycles, respectively, providing a practical route to versatile β-amino ketoxime and N-heteroaryl ethanamine derivatives. The amination products can be treated as isocyanate analogues and can be converted to other useful amino functionalities. An iridacyclic compound was isolated and identified as a plausible intermediate.
INHIBITION OF BACTERIAL BIOFILMS WITH ARYL CARBAMATES
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Page/Page column 33-34; 35, (2012/02/01)
Disclosure is provided for carbamate compounds that prevent, remove and/or inhibit the formation of biofilms, compositions including these compounds, devices including these compounds, and methods of using the same.
USE OF ARYL CARBAMATES IN AGRICULTURE AND OTHER PLANT-RELATED AREAS
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Page/Page column 42, (2012/03/26)
Disclosure is provided for methods of preventing, removing or inhibiting microbial biofilm formation or microbial infection in a plant or plant part thereof, including applying thereto a treatment effective amount of an aryl carbamate as described herein,
Synthesis and bacterial biofilm inhibition studies of ethyl N-(2-phenethyl) carbamate derivatives
Rogers, Steven A.,Whitehead, Daniel C.,Mullikin, Trey,Melander, Christian
supporting information; experimental part, p. 3857 - 3859 (2010/09/16)
An 88 member library based upon the marine bacterial metabolite ethyl N-(2-phenethyl) carbamate was evaluated for bacterial biofilm inhibition against a panel of medically relevant strains. These studies culminated in the discovery of a new class of molec
