124927-10-2Relevant academic research and scientific papers
Photochemical Reactions of Diphosphenes Carrying 2,4,6-Tris(trifluoromethyl)phenyl Group
Yoshifuji, Masaaki,Abe, Masatoshi,Toyota, Kozo,Goto, Kei,Inamoto, Naoki
, p. 1572 - 1575 (1993)
Photoreactions of 1,2-bisdiphosphene and 1-(2,4,6-tri-t-butylphenyl)-2-diphosphene were studied.The latter diphosphene gave formally an intramolecular cyclization product by photoirradi
Transition-metal Catalysed Metathesis of Phosphorus-Phosphorus Double Bonds
Dillon, Keith B.,Gibson, Vernon C.,Sequeira, Leela J.
, p. 2429 - 2430 (2007/10/03)
W(PMe3)6 is an efficient chloride ion abstracting reagent for the synthesis of RP=PR species from RPCl2 precursors; moreover, the W(PMe3)6-RPCl2 solutions catalyse the exchange of the diphosphene PR end-groups via a mechanism closely related to the olefin metathesis process.
Organometallic complexes of the diphosphene 2P2
Dillon, Keith B.,Goodwin, Helen P.
, p. 169 - 171 (2007/10/02)
Complexes of the symmetrical diphosphene 2P2 (ArP=PAr) containing the transition metal fragments Mo(CO)5, W(CO)5 and Pt(PEt3)Cl2 have been synthesised, and characterised by 31P NMR spectroscopy.The ligand is coordinated in an η1/su
Der 2,4,6-Tris(trifluormethyl)phenylsubstituent; Beispiele fuer elektronisch und sterisch stabilisierte niederkoordinierte Hauptgruppenelemente
Scholz, Mario,Roesky, Herbert W.,Stalke, Dietmar,Keller, Klaus,Edelmann, Frank T.
, p. 73 - 86 (2007/10/02)
An improved synthesis of 1,3,5-tris(trifluoromethyl)benzene (1) is reported.RFPCl2 (3), RFPH2 (4) and the unusually stable diphosphene RFP=PRF (5) are readily accessible starting from Li (2) (=
