124946-24-3Relevant articles and documents
1-CHLORO-1H-PHOSPHIRENES - A NEW SYNTHESIS FROM PHOSPHAALKENES AND CARBENES
Schnurr, Werner,Regitz, Manfred
, p. 3951 - 3954 (2007/10/02)
The chlorocarbenes 2, generated thermally from the diazirines 8, take part in -cycloaddition reactions with the phosphaalkenes 5 to furnish the dichlorophosphiranes 9.At 130 deg C, the latter products 9 undergo elimination of chlorotrimethylsilane to form the 1-chloro-1H-phosphirenes 4.