124957-76-2

Upstream product

• 124957-37-5 2-[Acetoxy-(2-methoxy-phenyl)-methyl]-acrylic acid methyl ester 
• 100-46-9 benzylamine 
• 115240-90-9 methyl 2-(hydroxy(2-methoxyphenyl)methyl)acrylate 
• 124957-43-3 methyl (2E)-2-(acetoxymethyl)-3-(2-methoxyphenyl)prop-2-enoate 
• 135-02-4 ortho-anisaldehyde 

Relevant academic research and scientific papers

Preparation d'amines allyliques a partir d'acyloxy-3 methylene-2 propionates de methyle substitues en 3 par un groupement aromatique ou heteroaromatique

The reaction of substituted methyl 3-acetoxy 2-methylene propionates 2 with aliphatic amines gives allylic amines.The E configuration is predominant.The reaction of esters 2 with aniline does not give allylic amines.These amines are prepared by rearrangement of the carbamates which are obtained by the reaction of phenyl isocyanate with methyl 3-hydroxy 2-methylene propionates 1.The primary allylic amines are prepared through the reduction of azides 11.