124964-79-0Relevant academic research and scientific papers
Functionalized Homocubanes: Oxidative Deiodination of Homocubyl Iodide. Synthesis of 4-Mesyloxy-, 4-Tosyloxy-, and 4-Chloro-1-bromopentacyclo2,5.03,8.04,7>nonan-9-one Ethylene Acetal from the Corresponding 4-Iodo-1
Moriarty, Robert M.,Khosrowshahi, Jaffar S.
, p. 855 - 856 (1989)
4-Iodo-1-bromopentacyclo2,5.03,8.04,7>nonan-9-one ethylene acetal (1) undergoes substitution via a ligand exchange process.
Functionalization of Cubanes and Homocubanes via Oxidative Displacement of Iodine Using Hypervalent Iodine
Moriarty, Robert M.,Khosrowshahi, Jaffar S.
, p. 1395 - 1404 (2007/10/02)
The iodo group in 4-iodo-1-carbomethoxycubane (1) can be replaced by mesyloxy, toxyloxy and chloro by oxidative displacement with C6H5I(OH)OMs, C6H5I(OH)OTs and C6H5ICl2, respectively.Similarly, the iodo group in the homocubyl compound 4-iodo-1-bromopenta
