125029-51-8Relevant articles and documents
THE SHERADSKY REARRANGEMENT OF α,α-DISUBSTITUTED CYCLOPENTANONE ARYLOXIMES: A SYNTHESIS OF THE SESQUITERPENES (+/-)-APLYSIN AND (+/-)-FILIFORMIN
Laronze, Jean-Yves,Boukili, Rachida El,Cartier, Dominique,Laronze, Jacqueline,Levy, Jean
, p. 2229 - 2232 (1989)
Lactols 6a,b, obtained by the Sheradsky rearrangement of aryloximes o, were alkylated in to 9a, in which three contiguous chiral centers were controlled.Cyclization of 9a gave the marine sesquiterpenes (+/-)-aplysin 11 and (+/-)-filiformin 13.