1250403-92-9Relevant academic research and scientific papers
Self-assembly of vesicles by a 2,6-di(7-benzamidy)quinolin-2-yl)pyridine derivative tuned by an amphiphilic amide chain
You, Liyan,Zhao, Xin,Li, Zhanting
, p. 1547 - 1552 (2010)
This paper describes 2-(2-(dioctylamino)-2-oxoethyl-amino)-2-oxoethoxyl (DOAOE)-tuned self-assembly of vesicles from a 2,6-di(7-benzamidy)-quinolin-2-yl)pyridine derivative. Scanning electron (SEM), transmission electron (TEM) and optical microscopy and d
P-Phenyleneethynylene-based comb-like oligomers: The synthesis and self-assembling property
Wang, Liu-Gang,Zhan, Tian-Guang,Zhao, Xin,Jiang, Xi-Kui,Li, Zhan-Ting
experimental part, p. 5303 - 5310 (2012/08/27)
This paper describes the self-assembling property of three series of p-phenyleneethynylene based comb-like oligomers, which carry multiple peripheral side chains of different polarity. The new oligomers are prepared readily through the formation of the hydrazone bonds from the corresponding aldehyde and gallic acid-derived benzohydrazides. In polar solvents such as methanol and ethanol, the oligomers that bear n-decyl or 2-(2-(dioctylamino)-2-oxoethyl- amino)-2-oxoethoxyl unit (DOAOE) segments as the side chains are revealed to form vesicular structures, while the oligomers carrying hydrophilic oligo(ethyleneglycol) side chains do not. The structures of the vesicles are evidenced by SEM, AFM, TEM, and dye-encapsulation experiments. UV-vis absorption spectroscopic experiments suggest that the vesicles are generated through the stacking of the conjugated backbones, which is promoted by the solvophobic interaction of the peripheral side chains.
Hydrogen-bonded benzylidenebenzohydrazide macrocycles and oligomers: Testing the robust capacity of an amide chain in promoting the formation of vesicles
Lu, Ben-Ye,Sun, Guang-Jun,Lin, Jian-Bin,Jiang, Xi-Kui,Zhao, Xin,Li, Zhan-Ting
scheme or table, p. 3830 - 3835 (2010/08/19)
This Letter describes 2-(2-(dioctylamino)-2-oxoethyl-amino)-2-oxoethoxyl (DOAOE)-tuned self-assembly of vesicles from rigid macrocycles and foldamer-like oligomers. The molecules are prepared through the formation of reversible hydrazone bonds from aldehy
