125085-00-9

Upstream product

• 125137-51-1 methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-acetyl-2-deoxy-2-isocyano-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 125084-87-9 3,4,6-tri-O-acetyl-2-deoxy-2-formamido-α-D-glucopyranosyl chloride 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 604-69-3 β-D-glucose pentaacetate 
• 125084-99-3 methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 76695-53-9 1,3,4,6-Tetra-O-acetyl-2-desoxy-2-formamido-β-D-glucose 

Relevant academic research and scientific papers

Gold(I)-Catalyzed Glycosylation with Glycosyl Ynenoates as Donors

A simple and versatile glycosylation method with both armed and disarmed glycosyl ynenoates as donors is developed. Employing a gold(I) complex as catalyst with or without the assistance of TfOH, the scope of the present glycosylation protocol is very wid

TMSBr-mediated solvent- and work-up-free synthesis of α-2-deoxyglycosides from glycals

The thio-additions of glycals were efficiently promoted by a stoichiometric amount of trimethylsilyl bromide (TMSBr) to produce S-2-deoxyglycosides under solvent-free conditions in good to excellent yields. In addition, with triphenylphosphine oxide as an additive, the TMSBr-mediated direct glycosylations of glycals with a large range of alcohols were highly α-selective.

tHE SYNTHESIS OF 2'-DEOXY-β-DISACCHARIDES: NOVEL APPROACHES

Benzylated 1,2-orthoacetates were converted by dry acetic acid into 1,2-trans-diacetates which behaved as excellent β-glycosyl donors with various non-acylated glycosyl acceptors in the presence of trimethylsilyl triflate.Deacetylation, followed by xantha

GLYCOSYLATIONS WITH N-FORMYLAMINO SUGARS: A NEW APPROACH TO 2'-DEOXY-β-DISACCHARIDES

Various derivatives of N-formyl glucosamine (β-acetate, α-chloride, α-trichloroacetimidate) are used as glycosyl donors.The resulting disaccharides are smoothly deaminated into the corresponding 2'-deoxy-β-disaccharides through intermediate isonitriles by