125164-90-1

Upstream product

• 41977-20-2 (2R,3S)-2,3-dihydroxy-1-methylcyclohexa-4,6-diene 
• 125164-89-8 (1S,4R,5R,6S)-1-Methyl-2,3-dioxa-bicyclo[2.2.2]oct-7-ene-5,6-diol 
• 108-88-3 toluene 
• 125227-24-9 (1R,4S,5R,6S)-1-Methyl-2,3-dioxa-bicyclo[2.2.2]oct-7-ene-5,6-diol 

Downstream Products

• 134680-69-6 4C-methyl-muco-inositol 
• 144782-83-2 (1S,2S,3S,4S,5S,6R)-6-Amino-2-methyl-cyclohexane-1,2,3,4,5-pentaol 
• 144782-83-2 (1S,2S,3S,4S,5R,6R)-6-Amino-2-methyl-cyclohexane-1,2,3,4,5-pentaol 
• 144782-89-8 (1S,2S,3S,4S,5R,6R)-6-Amino-1-methyl-cyclohexane-1,2,3,4,5-pentaol 

Relevant academic research and scientific papers

Enantiospecific Synthesis of C-Methyl Azidoinositols and Aminocyclitols from Toluene

The total synthesis of the homochiral C-methyl azidoinositols (9), (17) and (20), and the aminocyclitols (10), (18) and (21) from toluene has been achieved, via the key steps of microbial oxidation of toluene and photo-oxidation of the resulting cyclohexa

TOTAL SYNTHESIS OF (-)-LAMINITOL (1D-4C-METHYL-myo-INOSITOL) VIA MICROBIAL OXIDATION OF TOLUENE

The chiral cyclohexadienediol (4), available from oxidation of toluene by Pseudomonas putida, can be converted via selective epoxidation and ring-opening to the C-methyl conduritol F (8) and thence to (-) laminitol (2).

PHOTOCHEMICAL ROUTES FROM ARENES TO INOSITOL INTERMEDIATES: THE PHOTO-OXIDATION OF SUBSTITUTED cis-CYCLOHEXA-3,5-DIENE-1,2-DIOLS

Endoperoxides such as (6), (15), (16) and (20) are avaliable by microbial oxidation and photo-oxidation of arenes; u.v. photolysis of (6) yields mainly the βc-epoxyketone (9), and further photolysis gives (10) via photoepimerisation.