125226-88-2

Upstream product

• 86287-64-1 (2E,1'S,2'R,5'S)-but-2-enedioic acid bis(2'-isopropyl-5'methyl-cyclohexyl) ester 
• 542-92-7 cyclopenta-1,3-diene 
• 34675-24-6 di-L-menthyl fumarate 
• 92691-29-7 fumaric acid di(-)menthyl ester 

Downstream Products

• 198224-00-9 (1S,2R,3R,4R)-Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid bis-[((S)-2-chloro-1-phenyl-ethyl)-amide] 
• 198223-94-8 (1S,2R,3R,4R)-Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid bis-[((S)-2-hydroxy-1-phenyl-ethyl)-amide] 
• 5826-73-3 dimethyl carbate 
• 3813-52-3 (1S,2S,3S,4R)-3-carboxy-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ester 

Relevant academic research and scientific papers

Lewis-acid catalysis of the asymmetric Diels-Alder reaction of dimenthyl fumarate and cyclopentadiene

The effects of Lewis acid catalysts, solvent, catalyst loading, and temperature on the diastereomeric excess in the Diels-Alder reaction of (+)-dimenthyl fumarate and cyclopentadiene were investigated.

Enantioselective Diels-Alder reactions: Novel constrained bis(oxazoline) ligand-metal triflate catalysts

Five chiral 1,4-bis(oxazoline) ligands, each bearing a bicyclic backbone, were prepared and examined in Mg(OTf)2-, Zn(OTf)2, and Cu(OTf)2 catalyzed Diels-Alder reactions. The cycloadditions were carried out at room tempera

The effect of alumina on the Diels-Alder reactions of cyclopentadiene with menthyl acrylate and dimenthyl fumarate

Alumina catalyzes the Diels-Alder reactions of cyclopentadiene with optically active menthyl acrylate and dimenthyl fumarate. Significant diastereoselectivity is observed in each case.

ASYMMETRIC DIELS-ALDER REACTION. COOPERATIVE BLOCKING EFFECT IN ORGANIC SYNTHESIS

Remarkably high diastereoselectivity is observed in the organoaluminium catalyzed asymmetric Diels-Alder reaction of (-)-dimenthyl fumarate.