125239-02-3

Upstream product

• 125219-21-8 benzyl 2,3,6-tri-O-benzyl-4-deoxy-4-C-(methylene)-α-D-xylo-4-hexopyranoside 
• 125219-26-3 benzyl 2,3,6-tri-O-benzyl-α-D-xylo-hex-4-ulopyranoside 
• 58527-89-2 benzyl 1,2,3,6-tetra-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 125219-22-9 Benzyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(formyl)-α-D-galactopyranoside 
• 1344024-95-8 (4-deoxy-4-methyl-(1,2,3,6-tetra-O-benzyl-α-D-glucopyranosyl))-(2,3,4,6-tetra-O-benzyl)-α-D-glucopyranoside 
• 1344024-94-7 (4-deoxy-4-methyl-(1,2,3,6-tetra-O-benzyl-α-D-glucopyranosyl))-(2,3,4,6-tetra-O-acetyl)-β-D-galactopyranoside 
• 1344024-93-6 (4-deoxy-4-methyl-(1,2,3,6-tetra-O-benzyl-α-D-glucopyranosyl))-(2,3,4,6-tetra-O-acetyl)-β-D-glucopyranoside 
• 139071-01-5 Benzyl 4-C-(Acetoxymethyl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside 
• 139071-00-4 Benzyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(hydroxymethyl)-α-D-glucopyranoside 
• 139071-03-7 Benzyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulopyranos-1-yl)-α-D-glucopyranoside 
• 139071-06-0 Benzyl 2',6-Anhydro-2,3-di-O-benzyl-4-deoxy-4-C-(3',4',5',7'-tetra-O-benzyl-1'-deoxy-α-D-gluco-2-heptulopyranos-1'-yl)-α-D-glucopyranoside 
• 139071-02-6 Benzyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(iodomethyl)-α-D-glucopyranoside 
• 125219-23-0 Benzyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(formyl)-α-D-glucopyranoside 
• 125239-03-4 (S)-((4S,5R,6R)-3-Benzenesulfinyl-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-((2S,3R,4S,5R,6S)-4,5,6-tris-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yl)-methanol 
• 125239-03-4 (R)-((4S,5R,6R)-3-Benzenesulfinyl-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-((2S,3R,4S,5R,6S)-4,5,6-tris-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yl)-methanol 
• 125219-25-2 (4R,4aS,6R,7R,8S,8aR)-7,8-Bis-benzyloxy-6-benzyloxymethyl-2,2-dimethyl-4-((2S,3S,4S,5R,6S)-4,5,6-tris-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yl)-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 125219-27-4 (R)-((4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-((2S,3R,4S,5R,6S)-4,5,6-tris-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yl)-methanol 

Relevant academic research and scientific papers

Increased glycosidic bond stabilities in 4-C-hydroxymethyl linked disaccharides

Three new hydroxymethyl-linked non-natural disaccharide analogues, containing an additional methylene group in between the glycosidic linkage, were synthesized by utilizing 4-C-hydroxymethyl-α-D-glucopyranoside as the glycosyl donor. A kinetic study was u

Synthesis of Carbon-Bridged C-Lactose and Derivatives

4-C-Formylglucopyranoside 9 was readily obtained from 4-O-unprotected glucose derivative 4 in four steps, each step giving a high product yield.Reaction with 1-C-lithiated 2-phenylsulfinyl-D-galactal 10 as nucleophile furnished C-disaccharide intermediate

Spiroketal Synthesis. - A Case of Intramolecular Glycoside Bond Formation

From 4-O-unsubstituted glucose derivatives 1a, b the 4-hydroxymethyl-substituted glucose derivatives 9a, b were obtained via oxidation to the ketone, Wittig reaction with methylenetriphenylphosphorane, borane addition, and subsequent oxidation to yield th

SYNTHESIS OF CARBON BRIDGED C-DISACCHARIDES

Direct lithiation of the readily available 2-phenylsulfinyl-D-glucal 2 provides the 1-C-lithiated species 2A furnishing with 4-deoxy-4-formyl-D-glucose derivative 7 in a diastereocontrolled reaction the C-disaccharide intermediate 8.This compound is trans