125253-84-1

Basic information

• Product Name: 2-Butenenitrile,2-(dimethylamino)-4-oxo-,(E)-(9CI)
• Synonyms: 2-Butenenitrile,2-(dimethylamino)-4-oxo-,(E)-(9CI)
• CAS NO: 125253-84-1
• Molecular Formula: C6H8N2O
• Molecular Weight: 124.14
• Product Categories: AMINETERTIARY
• Mol File: 125253-84-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Butenenitrile,2-(dimethylamino)-4-oxo-,(E)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenenitrile,2-(dimethylamino)-4-oxo-,(E)-(9CI)(125253-84-1)
• EPA Substance Registry System: 2-Butenenitrile,2-(dimethylamino)-4-oxo-,(E)-(9CI)(125253-84-1)

Safety Data

• Hazardous Substances Data: 125253-84-1(Hazardous Substances Data)

Relevant articles and documents

1-Acceptor Substituted Vinamidinium Salts: Stability and Reactivity

1-Chloro- and 1,3-dichloro-vinamidinium salts react with potassium cyanide to afford 1-cyano- and 1,3-dicyano-vinamidinium salts.The former add nucleophiles at the C-3 position.MNDO calculations, competitive hydrolysis experiments and cyclic voltammetry reveal the following sequence of stabilities of vinamidinium salts: 1,3-(NMe2)2 > 1-NMe2 > 2-Aza > H > 2-(p-MeOC6H4) > 2-OMe > 2-Cl > 2-CN > 1,3-(SMe)2 > 1-Cl > 1-CO2Et > 2-NO2 > 1-CN > 1,3-(CN)2.Interestingly enough, reduction potentials show that 1,3-dicyanovinamidinium salt is more stable than a 1,3-dichlorovinamidinium salt, whereas a 1-chlorovinamidinium salt is more stable than a 1-cyanovinamidinium salt. - Keywords: Vinamidinium Salts, Hydrolysis, Cyclovoltammetry, MNDO Calculations