125261-50-9Relevant academic research and scientific papers
Preparation and Some Reactions of Tricyclo1,4>octan-2-ones and Tricyclo1,4>heptan-2-ones
Cotterill, Ian C.,Finch, Harry,Highcock, Rona M.,Holt, Robert A.,Mahon, Mary F.,et al.
, p. 1353 - 1366 (2007/10/02)
Bicyclooct-2-en-7-ones (1)-(4) provide the corresponding 2-bromo derivatives (5)-(15) through a range of highly stereoselective reactions.From chosen compounds in the latter series, the tricyclooctanones (16)-(22) were prepared.The tricycl
Synthesis and Some Reactions of 3,3,6-Trisubstituted Tricyclo1,4>heptan-2-ones
Finch, Harry,Highcock, Rona M.,Roberts, Stanley M.,Short, Kevin M.,Sik, Vladimir
, p. 670 - 672 (2007/10/02)
Electrophiles and most nucleophiles react with tricyclo1,4>heptan-2-ones with preferential cleavage of the C(1)-C(4) or C(1)-C(5) bond; X-ray data show the highly strained tricycloheptanone (14) has a bond angle of 149.2(9) deg at a tet
