125274-08-0Relevant academic research and scientific papers
E/Z product distribution in the metathesis of allyl alcohol derivatives with a first generation ruthenium-based catalyst
Moulins, Jonathan R.,Burnell, D. Jean
, p. 3992 - 3994 (2011)
Based on experiments with four simple derivatives of allyl alcohol, it has been shown that the product of cross-metathesis as mediated by a 'first generation' ruthenium catalyst increases in its proportion of the E-isomer as the reaction progresses. This increase is due to equilibration, which is also mediated by the ruthenium catalyst.
Carbon-halogen bond activation by Nickel catalyst: Synthesis of alkenes, from 1,2-dihalides
Malanga, Corrado,Mannucci, Serena,Lardicci, Luciano
, p. 1021 - 1028 (2007/10/03)
Unsaturated hydrocarbons can easily be prepared in a few seconds starting from 1,2 dibromides in the presence of a catalytic amount of Nickel diphenylphosphinoethane dichloride (NidppeCl2) and tri.n.butyl tin hydride, (TBTH) at room temperature. The dependencie of the nature of starting dihalides is investigated.
