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125278-10-6

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  • hot sale 99% (S)-1,1,1-trifluoropropan-2-amine CAS:125278-10-6 CAS NO.125278-10-6

    Cas No: 125278-10-6

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125278-10-6 Usage

General Description

L-2,2,2-TRIFLUORO-1-(METHYL)ETHYLAMINE is a chemical compound with the molecular formula C4H7F3N. It is a colorless liquid with a strong ammonia-like odor. L-2,2,2-TRIFLUORO-1-(METHYL)ETHYLAMINE is commonly used as an intermediate in the production of pharmaceuticals, agrochemicals, and other organic compounds. It is also used as a reagent in organic synthesis and as a solvent in various chemical reactions. L-2,2,2-TRIFLUORO-1-(METHYL)ETHYLAMINE is a highly reactive compound and should be handled with care, as it can cause irritation to the skin, eyes, and respiratory system.

Check Digit Verification of cas no

The CAS Registry Mumber 125278-10-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,5,2,7 and 8 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 125278-10:
(8*1)+(7*2)+(6*5)+(5*2)+(4*7)+(3*8)+(2*1)+(1*0)=116
116 % 10 = 6
So 125278-10-6 is a valid CAS Registry Number.
InChI:InChI=1/C3H6F3N/c1-2(7)3(4,5)6/h2H,7H2,1H3/t2-/m0/s1

125278-10-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name L-2,2,2-Trifluoro-1-(methyl)ethylamine

1.2 Other means of identification

Product number -
Other names L-1-Methyl-2,2,2-trifluoroethylamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:125278-10-6 SDS

125278-10-6Downstream Products

125278-10-6Relevant articles and documents

Chemoenzymatic dynamic kinetic resolution of α-trifluoromethylated amines: Influence of substitutions on the reversed stereoselectivity

Cheng, Guilin,Xia, Bo,Wu, Qi,Lin, Xianfu

, p. 9820 - 9828 (2013/09/02)

Enzymatic resolution of α-trifluoromethylated amines via kinetic resolution (KR), dynamic kinetic resolution (DKR) employing CALB-Pd/Al 2O3, and a one-pot sequential process of KR/DKR/KR was investigated comparatively for the first time. Although CALB-catalyzed KR of α-trifluoromethylated amines with substituents of methyl (1a), isopropyl (1c), phenyl (1d) and benzyl group (1e) can provide good stereoselectivity factors E from 31 to >200 respectively, DKR and sequential process of KR/DKR/KR possess better practical application potential because of the higher conversion (62%-84%) and the similar enantiomeric excesses (90%-99%). The enantiopreference and inversion for the α-trifluoromethylated amines displayed by CALB were observed and explained by docking modes. Namely, for 1,1,1-trifluoro-2-propylamine (1a), the product amide with R-configuration was obtained, and the enantiopreference was converted to S for the amines (1b-1e) with substituents larger than methyl group. The catalysts recycle, and scale-up experiments were demonstrated successfully. All these results indicated the high efficiency and green feature of this enzymatic process, and its application significance.

Fungicidal trifluoromethylalkylamino-triazolopyrimidines

-

, (2008/06/13)

An improved process for the preparation of (S)-1,1,1-trifluoroalkyl-2-amines of formula IIIA, STR1 where R1 is a C1-6 alkyl group, from the corresponding racemic mixture, which process includes treating 1 part by mole of the racemic mixture with approximately 0.3 to 0.7 part by mole of D-(-)-tartaric acid in the presence of an inert solvent.

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