125287-96-9

Upstream product

• 83051-88-1 methyl 6-aldehydo-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 125287-98-1 methyl [methyl 2,3,4-tri-O-benzyl-L-threo-β-D-gluco-octopyranosid]uronate 
• 125287-99-2 methyl [methyl 2,3,4-tri-O-benzyl-D-threo-α-D-gluco-octopyranosid]uronate 
• 115520-84-8 methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6(E)-eno-α-D-gluco-oct-1,5-pyranoside 
• 849035-33-2 methyl 4(S),5(S),6(R)-tri-O-benzyl-dec-2(E),7(E),9-trienoate 
• 116384-34-0 (2R,3S,4R,5E)-2,3,4-tribenzyloxyocta-5,7-diene-1-al 
• 122698-57-1 Dithiocarbonic acid S-methyl ester S-[1-((2S,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-allyl] ester 

Relevant academic research and scientific papers

Simple synthesis of D-erythro- and L-erythro-D-gluco-octoses

Synthesis of the previously unknown methyl 2,3,4-tri-O-benzyl-L-erythro-β-D-gluco-and D-erythro-α-D-gluco-oct-1,5-pyranosides (1 and 2) was accomplished on two independent routes via either cis-hydroxylation of stereoisomeric 6-C-vinyl-L-glycero-β-D-gluco

FROM SUGAR ALLYLTIN DERIVATIVES TO CHIRAL DIENOALDEHYDES AND TRIENOATES

Sugar dialdoses 5, 9, 15, and 16 were converted into allyltin derivatives 4, 12, 13, and 14, in yields of 35 - 47percent respectively.Treatment of 4, 12, and 13 with a mild Lewis acid (ZnCl2) in methylene chloride caused rearrangement to appropriate dieno

Higher-Carbon Sugars. Part 13. The Catalytic Osmylation of Some α,β-Unsaturated Octuronic Acid Derivatives and a Synthesis of (meso)-threo-gluco-Octitol

In compliance with Kishi's empirical rule, catalytic osmylation of methyl uronate (6) produced a mixture of methyl (methyl 2,3,4,-tri-O-benzyl-β-L-threo-D-gluco-octopyranosid)uronate