125290-99-5

Basic information

• Product Name: (1S,2S,3R,4S,5S,6S)-1-fluoro-2-O-(methyl)cyclohexane-2,3,4,5,6-pentol
• Synonyms: (1S,2S,3R,4S,5S,6S)-1-fluoro-2-O-(methyl)cyclohexane-2,3,4,5,6-pentol
• CAS NO: 125290-99-5
• Molecular Weight: 196.176
• Mol File: 125290-99-5.mol

Chemical Properties

• CAS DataBase Reference: (1S,2S,3R,4S,5S,6S)-1-fluoro-2-O-(methyl)cyclohexane-2,3,4,5,6-pentol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,3R,4S,5S,6S)-1-fluoro-2-O-(methyl)cyclohexane-2,3,4,5,6-pentol(125290-99-5)
• EPA Substance Registry System: (1S,2S,3R,4S,5S,6S)-1-fluoro-2-O-(methyl)cyclohexane-2,3,4,5,6-pentol(125290-99-5)

Safety Data

• Hazardous Substances Data: 125290-99-5(Hazardous Substances Data)

Upstream product

• 642-38-6 quebrachitol 

Downstream Products

• 1054658-35-3 Benzoic acid (1S,2R,3R,4S,5R,6S)-2,3,4-tris-benzyloxy-6-(1-ethoxy-ethoxy)-5-fluoro-cyclohexyl ester 
• 1054622-33-1 Benzoic acid (1R,2R,3R,4S,5S,6S)-2,3,4-tris-benzyloxy-5-fluoro-6-hydroxy-cyclohexyl ester 
• 143446-80-4 D-2,4,5,6-Tetra-O-benzyl-3-deoxy-3-fluoro-myo-inositol 1- 
• 143446-81-5 D-3-deoxy-fluoro-phosphatidylinositol 
• 143446-79-1 D-2,4,5,6-Tetra-O-benzyl-3-deoxy-3-fluoro-myo-inositol 1-(O-benzyl-N,N-diisopropylphosphoramidite) 
• 143446-78-0 D-2,4,5,6-Tetra-O-benzyl-3-deoxy-3-fluoro-1-O-(methoxymethyl)-myo-inositol 
• 142544-21-6 D-2,4,5,6-Tetra-O-benzyl-3-deoxy-3-fluoro-myo-inositol 
• 151071-93-1 D-4,5,6-Tri-O-benzyl-3-deoxy-3-fluoro-1-O-(methoxymethyl)-myo-inositol 
• 151071-90-8 D-4,5,6-Tri-O-benzyl-3-deoxy-3-fluoro-1,2-O-isopropylidene-myo-inositol 
• 143446-77-9 D-4,5,6-Tri-O-benzyl-3-deoxy-3-fluoro-myo-inositol 
• 847555-66-2 D-1-O-cyclohexylcarbamoyl-2-deoxy-2-fluoro-3-O-methyl-5,6-O-[(R/S)-2,2,2-trichloroethylidene]-chiro-inositol 
• 120444-24-8 D-3-deoxy-3-fluoro-myo-inositol 

Relevant articles and documents

Competition between non-classical single and double epimerizations in cyclitol chemistry

Two competitive regio- and stereoselective epimerization reactions were investigated in four cyclitols characterized by four contiguous OH groups with a cis-trans-trans sequence and by varied substituents (OMe, OBz, F, H) adjacent to this tetrol unit. The

D-2-Deoxy-2-fluoro-chiro-inositol-a new member of the deoxy fluoro inositol family

An efficient synthetic route to D-2-deoxy-2-fluoro-chiro-inositol has been developed with inversions of the C-1 and C-5 configuration of L-quebrachitol. The key steps of the route are two consecutive one pot epimerization procedures which do not require t

Synthesis and biological activity of the D-3-deoxy-3-fluoro and D-3-chloro-3-deoxy analogues of phosphatidylinositol

The naturally occurring inositol derivative, L-quebrachitol (1), serves as starting material for the synthesis of D-3-deoxy-3-fluoro- and D-3-chloro-3-deoxy-myo-inositol (4, 28). Their transformation into the title compounds 22 and 40 (abbreviated as FPI

A SIMPLIFIED ROUTE TO THE PHOSPHATIDYLINOSITOL CASCADE INHIBITOR - (-)-1L-1-DEOXY-1-FLUORO-MYO-INOSITOL

A two step synthesis of the title compound from the rubber serum byproduct, quebrachitol, is reported.