1253124-38-7Relevant academic research and scientific papers
Synthesis, characterization and pronounced epoxidation activity of cis-dioxo-molybdenum(VI) tridentate Schiff base complexes using tert-butyl hydroperoxide
Rezaeifard, Abdolreza,Sheikhshoaie, Iran,Monadi, Niaz,Alipour, Mahboubeh
, p. 2703 - 2709 (2010)
The synthesis and catalytic performance of novel cis-dioxo-Mo(VI) complexes containing simple ONO tridentate Schiff base ligands in the epoxidation of various olefins using tert-butyl hydroperoxide in desired times with excellent chemo- and stereoselectivity have been described. The study of turnover numbers and the UV-Vis spectra of the Mo complexes in the present epoxidation system indicate well the high efficiency and stability of the catalysts during the reaction. The electron-deficient and bulky groups on the salicylidene ring of the ligand promote the effectiveness of the catalyst.
