1253124-39-8Relevant academic research and scientific papers
A novel tridentate Schiff base dioxo-molybdenum(VI) complex: Synthesis, experimental and theoretical studies on its crystal structure, FTIR, UV-visible, 1H NMR and 13C NMR spectra
Saheb, Vahid,Sheikhshoaie, Iran,Stoeckli-Evans, Helen
, p. 29 - 36 (2012)
A new dioxo-molybdenum(VI) complex [MoO2(L)(H2O)] has been synthesized, using 5-methoxy 2-[(2-hydroxypropylimino)methyl]phenol as tridentate ONO donor Schiff base ligand (H2L) and MoO 2(acac)2. The ye
Synthesis, characterization and pronounced epoxidation activity of cis-dioxo-molybdenum(VI) tridentate Schiff base complexes using tert-butyl hydroperoxide
Rezaeifard, Abdolreza,Sheikhshoaie, Iran,Monadi, Niaz,Alipour, Mahboubeh
experimental part, p. 2703 - 2709 (2011/01/10)
The synthesis and catalytic performance of novel cis-dioxo-Mo(VI) complexes containing simple ONO tridentate Schiff base ligands in the epoxidation of various olefins using tert-butyl hydroperoxide in desired times with excellent chemo- and stereoselectivity have been described. The study of turnover numbers and the UV-Vis spectra of the Mo complexes in the present epoxidation system indicate well the high efficiency and stability of the catalysts during the reaction. The electron-deficient and bulky groups on the salicylidene ring of the ligand promote the effectiveness of the catalyst.
