1253191-89-7Relevant academic research and scientific papers
Gold-catalyzed glycosidations: Unusual cleavage of the interglycosidic bond while studying the armed/disarmed effect of propargyl glycosides
Kayastha, Abhijeet K.,Hotha, Srinivas
experimental part, p. 5269 - 5272 (2010/11/03)
Armed/disarmed effect of propargyl glycosides in the presence of AuBr 3 is studied. Observed that oxophilic AuBr3 cleaves interglycosidic bond of an armed disaccharide resulting in the formation of a disaccharide and a 1,6-anhydro sugar. Trisaccharides were obtained after fine tuning the reactivity of the glycosyl donor with different protecting groups.
