1253283-22-5Relevant academic research and scientific papers
Peptide/laccase cocatalyzed asymmetric α-oxyamination of aldehydes
Akagawa, Kengo,Kudo, Kazuaki
scheme or table, p. 3498 - 3501 (2011/09/14)
An asymmetric α-oxyamination could be successfully performed by a peptide catalyst and laccase. The combination of peptide catalysis and enzymatic air oxidation promoted the reaction smoothly in water without employing a metal reagent. The oxyaminated compounds could be obtained as both aldehyde and carboxylic acid products depending on the reaction conditions.
Metal-free direct asymmetric aminoxylation of aldehydes catalyzed by a binaphthyl-based chiral amine
Kano, Taichi,Mii, Haruka,Maruoka, Keiji
supporting information; experimental part, p. 6638 - 6641 (2010/11/05)
And I'm free, metal-free fallin': A metal-free direct asymmetric aminoxylation of aldehydes with the oxoammonium salt 1, generated in situ from TEMPO and benzoyl peroxide (BPO), was found to be catalyzed by a binaphthyl-based secondary amine (S)-2. This m
