1253404-92-0Relevant academic research and scientific papers
One-Pot Synthesis of Unsymmetric Diaryliodonium Salts from Iodine and Arenes
Lindstedt, Erik,Reitti, Marcus,Olofsson, Berit
, p. 11909 - 11914 (2017/11/24)
The first synthesis of unsymmetric diaryliodonium salts directly from iodine and arenes is presented. The methodology provides diaryliodonium salts with the trimethoxyphenyl (TMP) moiety as dummy group. The protocol avoids the customary use of iodoarenes,
Facile synthesis of Koser's reagent and derivatives from iodine or aryl iodides
Merritt, Eleanor A.,Carneiro, Vania M. T.,Silva Jr., Luiz F.,Olofsson, Berit
experimental part, p. 7416 - 7419 (2011/02/22)
The first one-pot synthesis of neutral and electron-rich [hydroxy(tosyloxy)iodo]arenes (HTIBs) from iodine and arenes is presented, thereby avoiding the need for expensive iodine(III) precursors. A large set of HTIBs, including a polyfluorinated analogue, can be obtained from the corresponding aryl iodide under the same conditions. The reaction proceeds under mild conditions, without excess reagents, and is fast and high-yielding. Together, the two presented routes give access to a wide range of HTIBs, which are useful reagents in a variety of synthetic transformations.
