125364-76-3Relevant academic research and scientific papers
From Unsymmetrical Diphosphene to New 1,3-Diphosphapropenes
Gouygou, Maryse,Bellan, Jacques,Escusie, Jean,Couret, Claude,Dubourg, Antoine,et al.
, p. 593 - 595 (1989)
The (Z) 1,3-diphosphapropenes (3) obtained from dihalogenocarbenes and unsymmetrical diphosphene (1), via diphosphiranes (2), show, by X-ray structure analysis of (3a), a special conformation involving a coplanar P=C double bond and phosphorus Ione pairs.
THE CARBENIC INSERTION INTO THE P-P BOND
Koenig, M.,Gouygou, M.,Tachon, C.,Ouatib, R. El,Etemad-Moghadam, G.
, p. 305 - 308 (2007/10/02)
The cycloaddition reactions on Phosphorus Chemistry has allowed a new development of the three membered ring organophosphorus compounds.Starting from functionalized diphosphiranes obtained by action of carbenes on diphosphenes, we have studied their ring opening reactions leading to carbon insertion into P-P bond.
