1253783-36-6

Basic information

• Product Name: (1R,2R)-9-oxo-9H-fluorene-2,7-disulfonic acid bis-[(2-aminocyclohexyl)amide]
• Synonyms: (1R,2R)-9-oxo-9H-fluorene-2,7-disulfonic acid bis-[(2-aminocyclohexyl)amide]
• CAS NO: 1253783-36-6
• Molecular Weight: 532.685
• Mol File: 1253783-36-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2R)-9-oxo-9H-fluorene-2,7-disulfonic acid bis-[(2-aminocyclohexyl)amide](CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R)-9-oxo-9H-fluorene-2,7-disulfonic acid bis-[(2-aminocyclohexyl)amide](1253783-36-6)
• EPA Substance Registry System: (1R,2R)-9-oxo-9H-fluorene-2,7-disulfonic acid bis-[(2-aminocyclohexyl)amide](1253783-36-6)

Safety Data

• Hazardous Substances Data: 1253783-36-6(Hazardous Substances Data)

Upstream product

• 13354-21-7 9-oxo-9H-fluorene-2,7-disulfonyl dichloride 
• 32044-22-7 (1R,2R)-1,2-diaminocyclohexane tartrate 

Relevant articles and documents

Asymmetric transfer hydrogenation of ketones in aqueous solution catalyzed by rhodium(III) complexes with C2-symmetric fluorene-ligands containing chiral (1R,2R)-cyclohexane-1,2-diamine

Two C2-symmetric bis(sulfonamide) ligands containing fluorene-chiral (1R,2R)-cyclohexane- 1,2-diamine were complexed to Rh III(Cp*) and used as catalyst to reduce aromatic ketones. The corresponding chiral secondary alcohols were obtained in 87-100percent ee and 85-99percent yield, under asymmetric transfer hydrogenation (ATH) conditions using aqueous sodium formate as the hydride source. With acetophenone, 94percent ee and 86-97percent yield was achieved with substrate/catalyst (S/C) ratio of 10,000.