125380-18-9Relevant academic research and scientific papers
Stereoselective Construction of Quaternary Carbons by the Reaction of Aldehydes with Allylic Chromium Reagents Prepared from 1,3-Diene Monoepoxides and CrCl2
Fujimura, Osamu,Takai, Kazuhiko,Utimoto, Kiitiro
, p. 1705 - 1706 (2007/10/02)
A vinyl-substituted β-hydroxy carbanion synthon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of LiI.The reagent reacts with aldehydes to afford R*,R* adducts stereoselectivity.
