1253967-20-2Relevant academic research and scientific papers
Aversatile palladium/triphosphane system for direct arylation of heteroarenes with chloroarenes at low catalyst loading
Roy, David,Mom, Sophal,Beauperin, Matthieu,Doucet, Henri,Hierso, Jean-Cyrille
supporting information; experimental part, p. 6650 - 6654 (2010/12/25)
Put a ring on it: The use of an air-stable, robust palladium/tridentate phosphane catalyst in direct C-H and C-Cl activation reactions is reported (see scheme; DMAc=N,N-dimethylacetamide, TBAB=tetra-n-butylammonium bromide). Electron-rich, electron-poor, and polysubstituted furans (X=O), thiophenes (X=S), pyrroles (X=NR5), and thiazoles were arylated with chloroarenes in the presence of the catalyst.
