125414-98-4Relevant articles and documents
REACTION OF BISTRIMETHYLSILYLPEROXIDE WITH 2-BENZOTHIAZOLYLALKYLLITHIUMS: AN UNPRECEDENTED DEMETHYLATION
Florio, S.,Troisi, L.
, p. 3721 - 3724 (2007/10/02)
Bistrimethylsilylperoxide 1 reacts with 2-benzothiazolylalkyllithiums 3 leading to alkylbenzothiazoles 2, and to benzothiazolylalkyl silyl ethers 4.The reacton of 1 with 3 leading to 2 represents the first example of demethylation of 1.The reaction of 2-benzothiazolyllithium 2g with 1 leads mainly to 2-hydroxybenzothiazole 2h.