1254176-30-1Relevant articles and documents
Efficient preparation of polyfunctional organometallics via directed ortho -metalation
Wunderlich, Stefan H.,Bresser, Tomke,Dunst, Cora,Monzon, Gabriel,Knochel, Paul
, p. 2670 - 2678 (2010)
Highly functionalized organometallics are efficiently prepared in larger quantities (up to 4 g) by directed ortho-metalation using the previously reported amide bases TMP2Mn2MgCl24LiCl (TMP=2,2,6,6-tetramethylpiperidyl), TMP2Fe2MgCl24LiCl and TMP3La3MgCl25LiCl. The resulting organometallics undergo various reactions with electrophiles like acid chlorides, alkyl iodides, or aldehydes and provide the corresponding products in good to excellent yields. Georg Thieme Verlag Stuttgart New York.