1254206-69-3

Basic information

• Product Name: methyl 4-[(2R,3R)-3-(benzyloxymethyl)-1-tritylaziridin-2-yl]-benzoate
• Synonyms: methyl 4-[(2R,3R)-3-(benzyloxymethyl)-1-tritylaziridin-2-yl]-benzoate
• CAS NO: 1254206-69-3
• Molecular Weight: 539.674
• Mol File: 1254206-69-3.mol

Chemical Properties

• CAS DataBase Reference: methyl 4-[(2R,3R)-3-(benzyloxymethyl)-1-tritylaziridin-2-yl]-benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-[(2R,3R)-3-(benzyloxymethyl)-1-tritylaziridin-2-yl]-benzoate(1254206-69-3)
• EPA Substance Registry System: methyl 4-[(2R,3R)-3-(benzyloxymethyl)-1-tritylaziridin-2-yl]-benzoate(1254206-69-3)

Safety Data

• Hazardous Substances Data: 1254206-69-3(Hazardous Substances Data)

Upstream product

• 1254206-54-6 (2S,3R)-2-(benzyloxymethyl)-3-(tributylstannyl)-1-tritylaziridine 
• 619-44-3 methyl 4-iodobenzoate 
• 619-42-1 4-methoxycarbonylphenyl bromide 

Relevant articles and documents

Stille coupling of an aziridinyl stannatrane

An aziridinyl stannatrane 8 couples with aryl or alkenyl halides RX under modified Stille conditions to afford substituted aziridines. Efficient coupling at room temperature is possible in the best examples in the presence of ( tBu3P

Metalated aziridines for cross-coupling with aryl and alkenyl halides via palladium catalysis

The palladium-catalyzed coupling of an aziridinylzinc chloride intermediate with alkenyl and aryl halides has been demonstrated. The method provides products with retention of aziridine stereochemistry. The utility of the coupling procedure is illustrated