1254356-72-3

Upstream product

• 63328-00-7 (2S)-O-(p-toluenesulfonyl)-N-(p-toluenesulfonyl)phenylalaninol 
• 132161-97-8 (S)-N-(1-Cyano-3-phenylpropan-2-yl)-4-methylbenzenesulfonamide 
• 3182-95-4 L-Phenylalaninol 
• 1254356-69-8 (S,E)-8-acetoxy-4-aza-3-benzyl-4-(p-toluenesulfonyl)-7-[(triethyl)silyl]oct-6-enenitrile 
• 1254356-24-5 (S,E)-4-aza-3-benzyl-8-hydroxy-4-(p-toluenesulfonyl)-7-[(triethyl)silyl]oct-6-enal 
• 88738-78-7 bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate 

Downstream Products

• 1254356-25-6 methyl (R,E,E)-6-aza-5-benzyl-10-bromo-6-(p-toluenesulfonyl)-9-[(triethyl)silyl]deca-2,8-dienoate 
• 1254356-76-7 methyl (R,E,E)-6-aza-10-bromo-5-isopropyl-6-(p-toluenesulfonyl)-9-[(triethyl)silyl]deca-2,8-dienoate 
• 1254356-27-8 (2R,4R,5R)-2-benzyl-4-(methoxycarbonylmethyl)-1-(p-toluenesulfonyl)-5-[1-{(triethyl)silyl}vinyl]piperidine 
• 1254356-28-9 (3R,4aR,5S,7S,7aR)-3-benzyl-5-methoxycarbonyl-2-(p-toluenesulfonyl)-7-[(triethyl)silyl]octahydro-1H-[2]pyrindine 
• 1254356-79-0 (2R,4R,5R)-2-isopropyl-4-(methoxycarbonylmethyl)-1-(p-toluenesulfonyl)-5-[1-{(triethyl)silyl}vinyl]piperidine 
• 1254356-80-3 (3R,4aR,5S,7S,7aR)-3-isopropyl-5-methoxycarbonyl-1-(p-toluenesulfonyl)-7-[(triethyl)silyl]octahydro-1H-[2]pyrindene 

Relevant academic research and scientific papers

Stereoselective synthesis of 2,4,5-trisubstituted piperidines via radical cyclization

A novel approach to 2,4,5-trisubstituted piperidines is reported, involving the 6-exo cyclization of stabilized radicals onto α,β-unsaturated esters. Only two of the four possible diastereoisomers are observed, with diastereomeric ratios ranging from 3:2