1254470-32-0Relevant articles and documents
Isolation of a zwitterionic dienegold(III) Complex intermediate in the direct conversion of enyne-amines to cyclopentadienes
Melchionna, Michele,Nieger, Martin,Helaja, Juho
, p. 8262 - 8267 (2010)
(Figure Presented) Golden ring: A route for the direct AuCl 3-catalyzed conversion of an enyne-amine into cyclopentadiene is reported. The mechanism for the catalysis is proposed and supported by a resting-state zwitterionic gold(III)cyclopentadiene structure (see figure).