1254975-69-3Relevant academic research and scientific papers
Catalytic Oxidative Dehydrogenative Coupling of Cage B-H/B-H Bonds for Synthesis of Bis(o-carborane)s
Wu, Ji,Cao, Ke,Zhang, Cai-Yan,Xu, Tao-Tao,Ding, Li-Fang,Li, Bo,Yang, Junxiao
, p. 5986 - 5989 (2019)
An efficient and succinct protocol for synthesis of bis(o-carborane) connected by a B-B bond via palladium catalyzed oxidative dehydrogenative coupling of cage B-H/B-H bonds was developed for the first time. A series of bis(o-carborane)s connected by B(4)
Palladium catalyzed/counter ion tuned selective methylation of o-carboranes
Cao, Ke,Zhang, Cai-Yan,Xu, Tao-Tao,Wu, Ji,Ding, Li-Fang,Jiang, Linhai,Yang, Junxiao
, (2019)
The palladium catalyzed/counter ion tuned selective methylation of 9-amide-o-carboranes on B(4) and B(12) has been developed, and a series of o-carborane derivatives decorated with various groups have been synthesized with moderate yields. The in situ for
A facile approach for the synthesis of nido-carborane fused oxazoles via one pot deboronation/cyclization of 9-amide-o-carboranes
Zhang, Cai-Yan,Cao, Ke,Xu, Tao-Tao,Wu, Ji,Jiang, Linhai,Yang, Junxiao
, p. 830 - 833 (2019)
A one pot deboronation/cyclization of 9-amide-o-carboranes for the synthesis of nido-7,8-carborane fused oxazole by cooperation of Pd(OAc)2, AgOAc and K2CO3 has been developed. A plausible mechanism involving an amide dire
Palladium catalyzed selective arylation of: O -carboranes via B(4)-H activation: Amide induced regioselectivity reversal
Xu, Tao-Tao,Cao, Ke,Zhang, Cai-Yan,Wu, Ji,Jiang, Linhai,Yang, Junxiao
, p. 13603 - 13606 (2018)
By changing the charge distribution of boron vertices via introducing an amide on cage B(9), the selective B(4) arylation of o-carboranes via Suzuki-Miyaura coupling has been developed. A series of o-carborane derivatives decorated with diverse active groups have been synthesized with moderate to good yields, which have been proved to be further transformed to a novel kind of tri-substituted nido-carborane fused oxazole with potential application in boron neutron capture therapy, organometallic as well as coordination chemistry.
Novel approach to aminocarboranes by mild amidation of selected iodo-carboranes
Sevryugina, Yulia,Julius, Richard L.,Hawthorne, M. Frederick
, p. 10627 - 10634 (2011/02/18)
A mild protocol for the palladium-catalyzed Buchwald-Hartwig amidation of icosahedral carboranes is described. Employing 2-dicyclohexylphosphino-2′- (N,N-dimethylamino)biphenyl (1) as a ligand and K3PO4as a base, benzamide, trifluoro
